Extention of Darken's Quadric Formalism to Dilute Multicomponent solutions

Srikanth, S and Jacob, K T (1989) Extention of Darken's Quadric Formalism to Dilute Multicomponent solutions. ISIJ International, 29 (2). pp. 171-174.



Darken's quadratic formalism is extended to multicomponent solutions. Equations are developed for the representation of the integral and partial excess free energies and enthalpies in dilute multicomponent solutions.Quadratic formalism applied to multicomponent solutions is thermodynmically consistent. The formalism is compared with the conventional second orderMaclaurin series or interaction parameter representaion and relations between them are derived. Advantages of the Quadratic formalism are discussed.

Item Type:Article
Official URL/DOI:http://www.jstage.jst.go.jp/browse/isijinternation...
Uncontrolled Keywords:Quadratic formalism; interaction parameters; enthalpy and entropy parameters; thermodynamic cosistency.
Divisions:NML Chennai
ID Code:435
Deposited By:Sahu A K
Deposited On:13 May 2010 12:05
Last Modified:30 Nov 2011 09:56
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