Abhilash, and Agarwal, Harshita and Meshram, Pratima and Meshram, Rohit B and Jha, Soni and Patel, J N and Soni, M K and Rokkam, Kiran and Mashruwala, Sheeba (2021) Green process for recovery of vanadium from hazardous spent contact process catalyst by oxalic acid: kinetics and mechanism. Separation Science and Technology (1.75).
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Abstract
This work aims to develop a green method for the recovery of vanadium from spent contact process catalyst (SVC) with 6–7% V2O5. The efficiency of leaching was evaluated using oxalic acid by varying pulp density, time, particle size, and temperature. It is found that with 0.25 M of oxalic acid, almost 98% V, 42% Fe and 24% Al was recovered in 2 h at 323 K and pulp density of 20% using <50 µm particle size. The leaching kinetics and mechanism was further established by characterizing the feed and residues by XRD and SEM. Separation of vanadium was performed using ion-exchange and precipitation.
| Item Type: | Article |
|---|---|
| Official URL/DOI: | https://10.1080/01496395.2021.1878222 |
| Uncontrolled Keywords: | Spent catalysts; oxalic acid;vanadium; recovery; characterization; separation |
| Divisions: | Metal Extraction and Forming |
| ID Code: | 8303 |
| Deposited By: | Mrs Pratima Meshram |
| Deposited On: | 16 Feb 2021 22:28 |
| Last Modified: | 16 Feb 2021 22:28 |
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