Observation of intermediate bands in Eu3+ doped YPO4 host: Li+ ion effect and blue to pink light emitter

Parchur, A K and Prasad, A I and Rai, S B and Tewari, R and Sahu, Ranjan K and Okram, G S and Singh, R A and Ningthoujam, R S (2012) Observation of intermediate bands in Eu3+ doped YPO4 host: Li+ ion effect and blue to pink light emitter. AIP Advances, 2 (3). 032119-1.

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This article explores the tuning of blue to pink colour generation from Li+ ion co-doped YPO4:5Eu nanoparticles prepared by polyol method at ∼100-120 °C with ethylene glycol (EG) as a capping agent. Interaction of EG molecules capped on the surface of the nanoparticles and/or created oxygen vacancies induces formation of intermediate/mid gap bands in the host structure, which is supported by UV-Visible absorption data. Strong blue and pink colors can be observed in the cases of as-prepared and 500 °C annealed samples, respectively. Co-doping of Li+ enhances the emission intensities of intermediate band as well as Eu3+. On annealing as-prepared sample to 500 °C, the intermediate band emission intensity decreases, whereas Eu3+ emission intensity increases suggesting increase of extent of energy transfer from the intermediate band to Eu3+ on annealing. Emission intensity ratio of electric to magnetic dipole transitions of Eu3+ can be varied by changing excitation wavelength. The X-ray photoelectron spectroscopy (XPS) study of as-prepared samples confirms the presence of oxygen vacancies and Eu3+ but absence of Eu2+. Dispersed particles in ethanol and polymer film show the strong blue color, suggesting that these materials will be useful as probes in life science and also in light emitting device applications

Item Type:Article
Official URL/DOI:http://dx.doi.org/10.1063/1.4739504
Uncontrolled Keywords:annealing, colour, disperse systems, doping, energy gap, europium, lithium, magnetic moments, magnetic transitions, nanofabrication, nanoparticles, photoluminescence, polymer films, ultraviolet spectra, visible spectra, X-ray photoelectron spectra, yttrium compounds
Divisions:Material Science and Technology
ID Code:5855
Deposited By:Dr. A K Sahu
Deposited On:28 Jul 2012 00:15
Last Modified:04 Sep 2012 11:04
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