Reduced parabolic rate constant at presence of Mn3O4 and MnFe2O4

Ebrahimifar, Hadi and Zandrahimi, Morteza (2010) Reduced parabolic rate constant at presence of Mn3O4 and MnFe2O4. Journal of Metallurgy and Materials Science, 52 (3). pp. 267-271.

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Official URL/DOI: http://www.indianjournals.com

Abstract

Long-term stability and oxidation resistance of AISI 430 ferritic stainless
steel which is employed as an interconnect in solid oxide fuel cells (SOFCs) for
intermediate temperature operation, can be ameliorated with a protective coating layer.
In this study the pack cementation method was employed to coat AISI 430 ferritic stainless
steel. Isothermal oxidation and cyclic oxidation were applied to evaluate the parabolic
rate constant. Spinels forming (Mn3O4 and MnFe2O4) during oxidation improves oxidation
resistance. The coated samples demonstrated lower kp in each test and it indicates that
the coating layer could have acted as a mass barrier against the outward diffusion of
cations specially Cr.

Item Type: Article
Uncontrolled Keywords: Solid oxide fuel cell, AISI 430 ferritic stainless steel, oxidation, parabolic rate constant
Subjects: Metallurgy
Divisions: Metal Extraction and Forming
Depositing User: Dr. A K Sahu
Date Deposited: 14 Mar 2011 05:40
Last Modified: 02 Sep 2026 20:25
URI: http://eprints.nmlindia.org/id/eprint/2573

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