Bhadani, S N and Tewari, M and Agrawal, A and Sekhar, K C (1994) Extraction-spectrophotometric determination of nickel as ni-(par)(2)-(ctab)(2) complex in polymetallic sea-bed nodules and steels. Fresenius journal of analytical chemistry, 349 (6). pp. 478-481.
Full text not available from this repository.
Abstract
A red, water-soluble complex of nickel with PAR can be extracted into chloroform with CTAB at pH 7.0. The system obeys Beer's law upto 0.5 mug/ml with a molar absorptivity of 45 200 L . mol-1 . cm-1 at 540 nm. Job's method of continuous variations revealed that the composition of the extracting species is 1:2:2 for nickel:PAR:CTAB. Based on this extraction, a highly sensitive and selective spectrophotometric method for the determination of nickel in polymetallic sea-bed nodules and in steels, after prior separation of iron and manganese, was developed. The standard deviation was 0.04 - 0.127 mug for 5 - 25 mug of nickel.
| Item Type: | Article |
|---|---|
| Official URL/DOI: | http://www.nmlindia.org |
| Uncontrolled Keywords: | Atomic-Absorption Spectrometry |
| Divisions: | Metal Extraction and Forming |
| ID Code: | 984 |
| Deposited By: | Sahu A K |
| Deposited On: | 11 Jun 2010 12:15 |
| Last Modified: | 13 Dec 2011 16:31 |
| Related URLs: |
Repository Staff Only: item control page
