Copper/manganese oxide catalyzed regioselective amination of quinoline N-oxides: An example of synergistic cooperative catalysis

Sahoo, T and Thakur, D and Panda, A B and Ghosh, S C (2021) Copper/manganese oxide catalyzed regioselective amination of quinoline N-oxides: An example of synergistic cooperative catalysis. Tetrahedron Letters, 83 .

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Abstract

An atom economical and efficient protocol for C-2 amination of quinoline N-oxides using our synthesized recyclable heterogeneous Cu–MnO catalyst has been reported here. Direct Csingle bondH aminations of heterocyclic N-oxides with secondary amine were carried out under base, and ligand-free conditions in good to excellent yields. The major advantage is that air is used as a sole oxidant and our catalyst is recycled several times.

Item Type:Article
Official URL/DOI:https://doi.org/10.1016/j.tetlet.2021.153415
Uncontrolled Keywords:Cu-MnO catalyst, amination, regioselective, quinoline N-oxides, C-H Functionalization
Divisions:Material Science and Technology
ID Code:9358
Deposited By:Dr Mita Tarafder
Deposited On:08 Feb 2023 10:44
Last Modified:08 Feb 2023 10:44
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