Sircar, J K and Mohanty, Ashok and Konar, J and Garain, Pijush K and Dhonge, S S (2011) Stability constant determination revisited : A voltammetric method of study of Lead-1, 10 phenanthroline complex. Journal of Metallurgy and Materials Science, 53 (1).
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Abstract
Pb(II)-1,10 phenanthroline complex was studied by Differential Pulse Polarography( DPP) in 1.0M KNO3 as supporting electrolyte at 25OC temperature. Cyclic
voltammogramme revealed that Pb (II) - nitrate behaves quasi-reversibly with EC mechanism in the supporting electrolyte. Both stepwise formation constant as well as
overall formation of the complex was followed using De Ford and Hume's procedure and overall stability constant b value of the complex was determined as 5.1474 x 1012 with complexation number of 3.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Pb(II)-1, 10 - Phenanthroline complex, Differential pulse polarography,Cyclic voltammetry. |
| Subjects: | Corrosion Science |
| Divisions: | Analytical Chemistry |
| Depositing User: | Users 74 not found. |
| Date Deposited: | 10 Feb 2012 09:47 |
| Last Modified: | 03 Sep 2026 06:01 |
| URI: | http://eprints.nmlindia.org/id/eprint/4751 |
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