Mechanochemical Synthesis of p-Nitro Calix[6]arene

Chennakesavulu, K and Bhaskar Raju, G (2010) Mechanochemical Synthesis of p-Nitro Calix[6]arene. Asian Journal of Chemistry, 22 (6). pp. 4947-4949.

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Abstract

A novel procedure was developed for the synthesis of p-nitro calix[6]arenes from p-tert-butyl calix[6]arene by mechanical activation. Mixture of p-tert-butyl calix[6]arene dissolved in dichloromethane, glacial acidic acid and anhydrous HNO3 was subjected to intense mechanical activation/agitation in planetary ball mill. The nitro substituted calix[6]arene with 97% purity. and 75% yield was formed within 2.5 h which otherwise takes several hours to complete the reaction.

Item Type:Article
Official URL/DOI:http://624TP
Uncontrolled Keywords:Mechanical activation; Nitration; Calix[n]arenes; CH3COOH/HNO3
Divisions:NML Chennai
ID Code:3095
Deposited By:Mr. G Shailendra Kumar
Deposited On:06 Jul 2011 14:10
Last Modified:07 Dec 2011 12:20
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