Extraction of manganese from Ferro-manganese slag

Abstract

In the present investigation an attempt has been made to recover manganese from ferro-manganese slag of ferro-alloy plant. Roasting and leaching are the techniques used to recover- manganese. Roasting has been carried out by mixing the slag with CaO and CaCO3, at 1200Cfor 2 hours. The leaching of the roasted mass has been carried out in ferric chloride solution alone, as well as in presence of sucrose in ferric chloride solution. The optimum condit-ions have been established by varying the parameters like concentration of leaching agent, percent solids, particle size of the slag, temperature and time of leaching. It is possible to recover 87% of manganese from the ferro-manganese slag of 200# at a temperature of 80°C, 2 hours of leaching time and 5% solids in 0. 154 M ferric chloride solution. It has been found that the presence of sucrose in ferric chloride solution enhances the rate & recovery)recovery of manganese from slag.