Investigation on Cu(II) adsorption on cobalt silicate precipitation tube (CSPT) in aqueous medium

Parmar, Kavita and Chongder, D and Bandopadhyay, N R and Bhattacharjee, S (2011) Investigation on Cu(II) adsorption on cobalt silicate precipitation tube (CSPT) in aqueous medium. Journal of Hazardous Materials, 185 . pp. 1326-1331.

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Abstract

Cu(II) adsorption on cobalt silicate precipitation tube (CSPT) in aqueous medium has been reported. These tubes are porous with negative surface sites having isoelectric point (IEP) at pH 4.4. Cu(II) adsorption data follow Langmuir isotherm. CSPT has high Cu(II) loading capacity, which is a function of both Cu(II) concentration and CSPT weight. Adsorption bond energy obtained from Langmuir isotherm suggests a physisorption process. The adsorption process is endothermic and spontaneous. Adsorption kinetics follows pseudo second order model with activation energy (15.4 KJ mol−1) typical for physisorption process.

Item Type:Article
Official URL/DOI:http://dx.doi.org/10.1016/j.jhazmat.2010.10.049
Uncontrolled Keywords:Cu(II); Cobalt silicate precipitation tubes; adsorption; kinetics.
Divisions:Corrosion and Surface Engineering
ID Code:1978
Deposited By:INVALID USER
Deposited On:19 Oct 2010 15:10
Last Modified:21 Nov 2011 17:33
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