Effect of Pb and Sb additions on the precipitation kinetics of AZ91 magnesium alloy

Balasubramani, N and Srinivasan, A and Pillai, U T S and Pal, B C (2007) Effect of Pb and Sb additions on the precipitation kinetics of AZ91 magnesium alloy. Materials Science and Engineering A, 457 (1-2). pp. 275-281.

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Abstract

Effect of Pb and Sb additions on the precipitation sequence and ageing kinetics of AZ91 alloy has been studied using the differential thermal analyzer, optical microscopy and scanning electron microscopy. The precipitation sequence in the AZ91 alloy is not altered whereas the enthalpy required for dissolution of β phases changes with respect to the individual additions of Pb and Sb. The quantitative analysis of activation energy calculated from the DTA results using Kissinger method demonstrates the activation energy required for the Mg17Al12 phase formation is decreased from 5.21 to 3.5821 kJ/mol with Pb addition whereas it is increased from 5.21 to 8.37 kJ/mol with Sb and these results are correlated with the ageing characteristics.

Item Type:Article
Official URL/DOI:http://dx.doi.org/10.1016/j.msea.2006.12.132
Uncontrolled Keywords:AZ91 alloy; Precipitation kinetics; Activation energy; Kissinger analysis; Microstructure
Divisions:Metal Extraction and Forming
ID Code:184
Deposited By:INVALID USER
Deposited On:26 Oct 2009 12:11
Last Modified:13 Dec 2011 16:09
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