Corrosion behavior of AlCuFeMn alloy in aqueous sodium chloride solution

Medium Entropy Alloy AlCuFeMn possesses high room temperature strength and oxidation endurance. In present
work, the aqueous corrosion resistance of the as-cast as well as low temperature oxidized AlCuFeMn alloy in 3.5
wt% NaCl solution, is explored. Equimolar proportions of high purity copper, manganese, iron, and aluminum
were arc melted and cast in a copper mold. The alloy primarily consists of a face-centered cubic and a bodycentered cubic phase. Potentiodynamic polarization tests on the alloy after low temperature surface oxidation
reveal an aqueous corrosion resistance comparable to AISI 304 steel and CoCrFeMnNi high entropy alloy. The Xray photoelectron spectroscopic studies confirmed that the free surface in the as-cast alloy is in partially oxidized
state. The same completely oxidizes after low-temperature surface oxidation. Such low temperature surface
oxidation improves pitting corrosion resistance in AlCuFeMn alloy due to increased metal/oxide layer resistance.
The electrochemical impedance spectroscopy tests coupled with microscopy confirmed that the principal
corrosion mechanisms in the alloy are of the uniform and pitting type. The energy dispersive spectroscopy experiments indicate that a copper oxide enriched layer is formed on the surface oxidized specimen during
corrosion.