Das, N N and Dash, A and Brahama, G S and Mohapatra, P (2003) Synthesis, characterisation and dissociation of a glycinate bridged trinuclear Co(III)-Cu(II)-Co(III) complex. Inorganic Reaction Mechanisms , 5 (1). pp. 73-77.
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Abstract
A trinuclear complex, [{(NH3)(5)Co(O2CCH2NH))(2)Cu](ClO4)(6).2H(2)O has been synthesised using mononuclear glycinato(pentaammine)cobalt(III) perchlorate and characterised by various physicochemical methods. The kinetic study by stopped-flow spectrophotometer indicated that the dissociation of the trinuclear complex occurred mainly through an acid catalysed path.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | cobalt(III); copper(II); glycinate; trinuclear complex; dissociation kinetics |
| Subjects: | Materials Science |
| Divisions: | Material Science and Technology |
| Depositing User: | Users 5 not found. |
| Date Deposited: | 19 Jul 2011 05:21 |
| Last Modified: | 14 Dec 2011 09:12 |
| URI: | http://eprints.nmlindia.org/id/eprint/3442 |
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